Applied biochemistry and bioengineering - download pdf or read online

By Lemuel B Wingard; Ephraim Katchalski-Katzir; Leon Goldstein

ISBN-10: 0120411016

ISBN-13: 9780120411016

ISBN-10: 0120411024

ISBN-13: 9780120411023

ISBN-10: 0120411032

ISBN-13: 9780120411030

ISBN-10: 0120411040

ISBN-13: 9780120411047

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13, w h e r e the modulus used to characterize t h e interplay of reaction and diffusion is defined by the relationship 33 Heterogeneous Enzyme Reactors (7) w h e r e L is a characteristic d i s t a n c e , defined b y the ratio of the v o l u m e and external surface a r e a of t h e s u p p o r t , Deff is t h e effective diffusion coefficient in the p o r o u s m a t r i x , a n d V^ax is t h e m a x i m u m r a t e p e r unit v o l u m e . As before, simple M i c h a e l i s - M e n t e n kinetics are a s s u m e d in cal­ culating the results p r e s e n t e d in Fig.

15. The ratio of CSTR to PFR volumes required to achieve a given degree of conver­ sion for η = 1. The throughput rate and kinetic parameters are assumed to be the same for the two types of reactors, and Michaelis-Menten kinetics have been used. V. T H E O R Y O F O P E N T U B U L A R H E T E R O G E N E O U S ENZYME R E A C T O R S (OTHERs) WITH SEGMENTED FLOW A. T r a n s p o r t P h e n o m e n a in S e g m e n t e d F l o w In a segmented flow, the c o n c e n t r a t i o n and velocity fields are consider­ ably m o r e c o m p l e x t h a n in a c o r r e s p o n d i n g h o m o g e n e o u s flow, d u e to t h e induced s e c o n d a r y fluid motion.

Effect of Axial Dispersion A n important factor contributing to nonideal P F R r e a c t o r b e h a v i o r is axial dispersion. Both molecular diffusion and nonuniform velocity p r o ­ files contribute to the axial dispersion of material in laminar flow. T h e sit­ uation is further complicated in turbulent flow by the ' * e d d y " t r a n s p o r t of material from o n e fluid region to a n o t h e r . A detailed analysis of axial dis­ persion in laminar flow through t u b e s is carried out in the following sec­ tion (see Section V,C).

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Applied biochemistry and bioengineering by Lemuel B Wingard; Ephraim Katchalski-Katzir; Leon Goldstein

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